云南禄丰鹅头厂铁铜矿床中稀土矿物的发现及意义     

温利刚  曾普胜  詹秀春  范晨子  王广  孙冬阳  袁继海  费晓杰 《岩石矿物学杂志》2019,38(4):477-497

云南禄丰鹅头厂铁铜矿床是滇中地区著名的元古宙含铜富铁矿床之一,矿床中除了铁、铜等资源外,还伴生少量的稀土组分。本文利用国际上矿物与地质行业前沿的矿物自动分析测试方法——矿物表征自动定量分析系统(AMICS),结合扫描电镜-能谱(SEM-EDS)显微结构原位分析技术,完成了常规岩矿鉴定手段难以完成的矿物定量识别和鉴定,首次在禄丰鹅头厂铁铜矿床中发现了氟碳钙铈矿、氟碳铈矿、褐钇铌矿等独立的稀土矿物。其中,氟碳钙铈矿主要富集在条纹条带状矿石中,分布极不均匀,局部富集,主要呈微细粒半自形至它形粒状晶体,多为微细粒的不规则粒状集合体,与磁铁矿间隙中的方解石和绿泥石等脉石矿物紧密共生,在氟碳钙铈矿颗粒中普遍含有呈板状或柱状、片状、针状的微细粒氟碳铈矿;褐钇铌矿也主要富集在条纹条带状矿石中,呈细小的不规则粒状,与铁氧化物边缘缝隙中的绿泥石等脉石矿物紧密共生。X射线能谱分析表明,氟碳钙铈矿和氟碳铈矿富含轻稀土元素,以Ce、Nd、La为主,含量一般Ce La Nd,含少量Pr、Y等元素;褐钇铌矿中主要金属元素有Nb、Y、Ce、Nd、Fe、Ti、Mg、Ca、U等,其中Nb的含量较高,稀土元素以Y为主,并含少量Ce、Nd等。稀土矿物的发现,对探讨该矿床及整个滇中地区前寒武纪(中元古代)铁-铜(-稀土)矿床的成因有着一定的指示意义。根据矿床中稀土-铁氧化物的产出特征和区域成矿地质背景,结合前人研究成果,认为鹅头厂矿床中稀土-铁氧化物的形成与Columbia超大陆裂解时的深部(地幔)岩浆活动有关,并受到多期次后期热液事件的叠加改造。  相似文献   

西南地区稀散元素伴生成矿的主要类型及伴生富集规律   总被引：1，自引：0，他引：1  

陶琰  胡瑞忠  唐永永  叶霖  戚华文  樊海峰 《地质学报》2019,93(6):1210-1230

西南地区稀散元素资源丰富,主要以伴生元素矿床产出,寄主矿床类型主要为沉积岩容矿型铅锌矿(伴生Cd、Ge、Ga、Tl)、锡石硫化物矿床(伴生In、Cd)和沉积型铝土矿(伴生Ga)及含锗煤等。这些矿床往往集中产出,主要分布在三江铅锌铜银多金属矿成矿域、川滇黔铅锌多金属成矿域、滇东南锡多金属矿成矿域、黔西北铝土矿含矿带及滇西第三系含煤盆地。本文以滇东南锡石硫化物矿床(个旧、都龙、白牛场)及沉积岩容矿型铅锌矿(包括兰坪金顶铅锌矿和川滇黔铅锌银多金属成矿域中的会泽、大梁子、天宝山和富乐铅锌矿等)等为主要对象,开展了不同金属硫化物中稀散元素含量及电子探针面扫描分析,查定了稀散元素伴生富集的赋存状态,并在矿床地球化学研究基础上,综合分析了这些稀散元素的伴生富集规律。研究结果进一步表明,稀散元素(In、Cd、Ge、Ga、Tl)伴生富集都具有明确的载体矿物专属性:热液矿床中In、Cd、Ge、Ga主要富集在闪锌矿中,Tl主要富集在黄铁矿中;沉积铝土矿中Ga的载体矿物主要是一水铝石,含锗煤中Ge主要以有机质结合态赋存在腐殖体中。在伴生富集规律上,In主要伴生富集在锡石硫化物矿床中,滇东南三大锡石硫化物矿床(个旧、都龙、白牛场)具有相似的地质地球化学特征,成因上与燕山晚期花岗岩侵入密切相关。沉积岩容矿型铅锌矿普遍含有Cd、Ge、Ga、Tl,但不同矿床在不同稀散金属富集程度上存在明显差异,其中,金顶矿床中的闪锌矿高度富Cd,平均含量达1.23%,其成因可能与生物有机作用有关。临沧盆地西缘含锗煤产出在以花岗岩为基底的帮卖陆相含煤碎屑岩盆地中,具有工业意义的Ge只集中在第一含煤段的煤层中,其含煤段有硅质岩和薄层含碳硅质灰岩,在上部缺乏硅质岩的两个含煤段的煤中无Ge矿化。Ga在铝土矿中的伴生富集具有全球性特点,不同成矿时代和不同工业类型铝土矿中都具有镓的伴生富集,含量一般在50×10~(-6)～200×10~(-6),贵州铝土矿床主要形成于石炭纪,其矿石以硬水铝石及少量黏土等为主,Ga含量在70×10~(-6)～143×10~(-6),略高于中国和世界铝土矿中镓的平均值。  相似文献   

内蒙双尖子山Pb- Zn- Ag矿床金属矿物学研究与银的富集机理     

权晓莹  刘春花  孙洪军  王丰翔 《地质学报》2019,93(9):2308-2329

双尖子山Pb- Zn- Ag矿床位于黄岗- 甘珠尔庙多金属成矿带的东北段,是目前发现的中国最大的银矿床。本文通过野外地质调查、矿相学鉴定、电子探针背散射图像以及电子探针化学成分分析,对该矿床金属矿物的矿物学特征进行了详细研究,同时对金属矿物的化学式进行了计算,并对银的富集机理进行了探讨。银矿物主要以可见银(>50μm)的形式产出,包括独立银矿物：硫锑铜银矿、硫银锡矿、辉硒银矿、深红银矿、脆银矿、黝锑银矿、螺状硫银矿、金银矿和自然银等;不可见银含量少,主要以类质同象形式赋存在方铅矿中。矿床成矿阶段细分为：①石英- 高Fe闪锌矿- 富Se和Bi的方铅矿- 富Se富Sb富Sn的银矿物阶段;②石英- 方铅矿- 富Fe闪锌矿- 毒砂- 富Sb富Sn少Se的银矿物阶段;③石英- 闪锌矿- 方铅矿- 银矿物阶段;④黄铁- 碳酸盐阶段。金属矿物沉淀顺序为：(黄铁矿、黄铜矿、闪锌矿、方铅矿)→银的硫盐矿物→银的硫化物→自然银。矿床中的Fe+、Cu+、Zn+、Pb+、Ag+等金属离子在早期中温高硫逸度阶段主要以硫氢络合物形式搬运。随着成矿热液温度的降低,铅、锌等金属硫氢络合物开始分解,方铅矿、黄铜矿和闪锌矿等硫化物得以沉淀,此时部分银以显微和次显微包体银的形式被包裹于这些硫化物中,铅锌硫化物的大量沉淀引起成矿热液组成和性质的显著变化,最终导致银从硫氢络合物中彻底解体,并与Cu+、Sb3+等离子结合形成大量独立银矿物(如深红银矿、硫锑铜银矿等)。随着温度、盐度持续降低,硫逸度也逐渐降低,pH值升高,成矿流体中出现大量自由Ag+并逐渐达到饱和,银矿物开始大量沉淀,Ag+与H2S发生作用形成螺状硫银矿。自然银的大量出现标志着银的沉淀过程趋于结束。金属矿物沉淀顺序为：(黄铁矿、黄铜矿、闪锌矿、方铅矿)→银的硫盐矿物→银的硫化物→银的自然金属。  相似文献   

Clay‐coat diversity in marginal marine sediments     

Luke J. Wooldridge  Richard H. Worden  Joshua Griffiths  James E. P. Utley 《Sedimentology》2019,66(3):1118-1138

The specific mineralogy of clay grain coats controls the ability of the coat to inhibit quartz cementation in sandstones during prolonged burial and heating. How and why clay‐coat mineralogy varies across marginal marine systems is poorly understood, even though these eogenetic phenomena strongly influence subsequent mesodiagenesis and reservoir quality. The novel development of the ability to predict the distribution of clay‐coat mineralogy would represent an important development for sandstone reservoir quality prediction. In marginal marine sediments, clay minerals occur as grain‐coats, floccules, mud intraclasts, clay‐rich rock fragments or as dispersed material. However, the relationships between clay mineralogy, the amount of clay, and its distribution is poorly understood. This study focused on the Ravenglass Estuary, UK. The key aim was to develop and apply a novel methodology utilising scanning electron microscope – energy dispersive spectrometry, for the first time, on grain coats in modern sediments, to differentiate the clay‐coat mineral signature from that of the bulk sediment, and reveal the distribution of clay minerals across marginal marine sediments. The study showed that marginal marine sediments principally have their clay mineral assemblage present as clay‐coats on sand grains. These clay‐coats have a mixed clay mineralogy and are spatially heterogeneous across the range of marginal‐marine depositional environments. The study further showed that clay‐coat mineralogy is governed initially by the hydrologically‐controlled segregation of the clay minerals within inner estuarine depositional environments, and subsequently by the selective abrasive removal of specific clay mineral types during reworking and transport into the outer estuary and the marine environment. The highest relative abundance of grain‐coating chlorite was in sand‐flat and tidal‐bar depositional environments. The availability of an analogue data set, and an understanding of the controlling processes of clay‐coat mineralogy, offer crucial steps in building a predictive capability for clay‐coat derived elevated reservoir quality in deeply buried sandstones.  相似文献   

激光能量密度对LA-ICP-MS分析数据质量的影响研究   总被引：3，自引：2，他引：1  

王辉  汪方跃  关炳庭  盛兆秋 《岩矿测试》2019,38(6):609-619

LA-ICP-MS分析矿物元素含量时激光能量密度会影响样品的剥蚀速率,从而影响测试过程的信号强度。激光能量密度变化对测试数据精确度的影响,以及不同天然矿物对激光能量密度的响应尚需进一步明确。本文测定了不同莫氏硬度天然矿物可稳定剥蚀的最小激光能量密度,评估了193nm ArF准分子激光系统中能量密度对地质标准样品(NIST SRM614、USGS BCR-2G、USGS GSC-1G)和天然矿物测试数据质量的影响。研究结果表明:①稳定剥蚀石英和萤石所需的最小激光能量密度为4～5J/cm~2,低于前人的报道值(10J/cm~2),而稳定剥蚀其他矿物(如滑石、磷灰石、刚玉等)所需的最小能量密度一般在1～2J/cm~2;②不同激光能量密度剥蚀条件下,标准样品中大部分微量元素测试结果与推荐值的相对误差小于20%,相对标准偏差(RSD)小于10%,而天然矿物中含量1μg/g的大部分微量元素测试数据的RSD小于20%;③在一定范围内,激光能量密度越大,数据平均相对误差越小,整体质量更好。  相似文献   

Stable carbon isotope evidence for tracing the diet of the host <Emphasis Type="Italic">Hepialus</Emphasis> larva of <Emphasis Type="Italic">Cordyceps sinensis</Emphasis> in the Tibetan Plateau     

Di Chen  JianPing Yuan  ShiPing Xu  XiaoGang Zhou  Yan Zhang  XiaoMing Xu  ZhiWen Zou  GuRen Zhang  JiangHai Wang 《中国科学D辑(英文版)》2009,52(5):655-659

Two types of Hepialus larvae with different diets were distinguished in the Sejila Mountain, Tibetan Plateau based on the stable carbon isotope data of the host Hepialus larva of Cordyceps sinensis and its closely adjacent tender plant roots and humus fractions. Type I is the larva chiefly fed by soil humus, and characterized by the δ ¹³C values of −22.6‰ to −23.4‰, and more than −23.4‰ in its heads. Type II is the larva chiefly fed by tender plant roots, and characterized by the δ ¹³C values of −24.6‰ to −27.6‰, and less than −24.6‰ in its heads. Our result has exceeded the traditional understanding that their food sources only come from the tender plant roots, and may provide evidence for choosing cheap and high-quality foods and further establishing artificial habitats in their large-scale reproduction. Supported by the National Key Technology R & D Program (Grant No. 2007BAI32B05)  相似文献   

短波红外光谱矿物测量技术在普朗斑岩铜矿区热液蚀变矿物填图中的应用   总被引：17，自引：3，他引：14  

连长云  章革  元春华 《矿床地质》2005,24(6):621-637

利用便携式短波红外光谱测量仪（PIMA）在云南普朗斑岩铜矿区开展了短波红外光谱测量工作,通过系统的野外数据采集,获得了研究区蚀变矿物组合及主要蚀变矿物的分布,并建立了普朗斑岩铜矿区蚀变矿物分带模式。在此基础上,建立了斑岩铜矿床找矿模型,该模型对普朗铜矿区及其外围的找矿工作具有积极的指导意义。  相似文献   

腾冲地震台数字化水温观测数据异常分析     

段胜朝  曾庆堂  孙自刚  马志刚  杨铭昌 《地震地磁观测与研究》2017,38(6):86-91

腾冲地震台数字化水温记录多次出现数据突跳,影响观测资料质量。引入1套相同型号的水温仪进行对比观测,对可能引起原水温仪数据突跳的因素(静电干扰、供电电压、仪器探头故障等)进行一一排查,结果表明,水温仪主机数据转换模块工作不正常是引起水温数据突跳、阶变的主要原因,仪器供电电压不稳、雷电因素对数据突跳的产生有促进作用。消除水温数据突跳干扰的有效解决办法是更换1套水温观测仪器。  相似文献   

THE GEOLOGICAL AND ROCK MECHANICAL DISTINCTION EVIDENCE BETWEEN STICK-SLIP AND CREEP IN HOST ROCK SEGMENTS OF FAULT          下载免费PDF全文

ZHOU Yong-sheng 《地震地质》2019,41(5):1266-1272

Paleo-seismic and fault activity are hard to distinguish in host rock areas compared with soft sedimentary segments of fault. However, fault frictional experiments could obtain the conditions of stable and unstable slide, as well as the microstructures of fault gouge, which offer some identification marks between stick-slip and creep of fault. We summarized geological and rock mechanical distinction evidence between stick-slip and creep in host rock segments of fault, and analyzed the physical mechanisms which controlled the behavior of stick-slip and creep. The chemical composition of fault gouge is most important to control stick-slip and creep. Gouge composed by weak minerals, such as clay mineral, has velocity weakening behavior, which causes stable slide of fault. Gouge with rock-forming minerals, such as calcite, quartz, feldspar, pyroxene, has stick-slip behavior under condition of focal depth. To the gouge with same chemical composition, the deformation mechanism controls the frictional slip. It is essential condition to stick slip for brittle fracture companied by dilatation, but creep is controlled by compaction and cataclasis as well as ductile shear with foliation and small fold. However, under fluid conditions, pressure solution which healed the fractures and caused strength recovery of fault, is the original reason of unstable slide, and also resulted in locking of fault with high pore pressure in core of fault zone. Contrast with that, rock-forming minerals altered to phyllosilicates in the gouges by fluid flow through degenerative reaction and hydrolysis reaction, which produced low friction fault and transformations to creep. The creep process progressively developed several wide shear zones including of R, Y, T, P shear plane that comprise gouge zones embedded into wide damage zones, which caused small earthquake distributed along wide fault zones with focal mechanism covered by normal fault, strike-slip fault and reverse fault. However, the stick-slip produced mirror-like slide surfaces with very narrow gouges along R shear plane and Y shear plane, which caused small earthquake distributed along narrow fault zones with single kind of focal mechanism.  相似文献   

基于东道国因素的我国企业国际化研发网络节点选择     

李林  张柏林  何建洪 《世界地理研究》2019,28(6):11-21

在经济全球化的背景下，我国企业要保持竞争力并且实现对发达国家企业的技术赶超成为具有国际影响力的跨国公司，必须进行国际化研发。目前，以华为、中兴和长安为代表的跨国企业尝试构建国际化研发网络，先后在发达国家设立技术研发中心。然而，国际化研发作为知识和资本密集型投资对共担风险和知识独占有着双重需求，加之我国与发达国家之间存在技术落差、文化兼容和政策激励差异等不确定性因素，导致我国企业国际化研发选址同时面临外来者劣势、来源国劣势和新兴者劣势。本研究运用二元选择模型，分析东道国因素对我国企业国际化研发网络节点选择的影响。结果表明：市场规模、制度质量和我国企业在东道国形成的集聚效应对企业的国际化研发网络节点选择有显著的吸引作用，而研发投入积极影响企业研发网络节点选择，但是作用不显著。此外，集聚效应在其中起着显著的调节作用，我国企业在东道国的集聚效应越高，市场规模与国际化研发网络节点的正向关系得到加强，而研发投入与国际化研发网络节点选择的正向关系得到减弱。  相似文献